Clay nanotube Pickering emulsions for spill oil bioremediation and catalytic formulations

The Design of Synergistic Dispersant and Herding Systems using Tubular Clay Structures and Gel Phase Materials

DOI:
10.7266/N73X8533
 
UDI:
R5.x288.000:0001
Last Update:
Apr 28 2016 01:07 UTC
 
Dataset Author(s):
Renata Munillina, Abhishek Panchal, Yuri Lvov, Rawil Fakhrullin
Point of Contact:
Lvov, Yuri M.
Louisiana Tech University / Institute for Micromanufacturing
911 Hergot Ave
Ruston, Louisiana  71272
USA
ylvov@latech.edu
Funding Source:
RFP-V
 
Extent Description:
The work is related to developing an efficient oil-dispersant and bioremediation formulation with halloysite clay nanotubes which is designed to work in any place of oil spill. This dataset contains laboratory data, no field sampling involved.

Identified Submitted In-Review Available
3 3 3 3

Suggested Citation:

Renata Munillina, Abhishek Panchal, Yuri Lvov, Rawil Fakhrullin. 2016. Clay nanotube Pickering emulsions for spill oil bioremediation and catalytic formulations. Distributed by: Gulf of Mexico Research Initiative Information and Data Cooperative (GRIIDC), Harte Research Institute, Texas A&M University–Corpus Christi. doi:10.7266/N73X8533

Abstract:

The data involves chiefly, the use of halloysite clay nanotubes (HNT) in forming Pickering emulsions with oil and water. The halloysites were functionalised using octadecyltrimethoxysilane (ODTMS) and hexadimethylsilane (HMDS) in order to hydrophobize the halloysite and form better Pickering emulsions. The bacterial affinity of halloysites in general and modified halloysite was tested using the bacterial strain, Alcanivorax borkumensis. The bacteria was obtained from ATCC and was used in several toxicity and emulsion experiments. The onus of the study was to study the affinity of the oil-degrading bacteria to HNTs and hydrophobized HNT and the resultant toxicity.

Purpose:

Developing better herding and dispersant systems for oil bioremediation using halloysite clay nanotubes

Theme Keywords:

halloysite, oil, bioremediation, dispersant, toxicity

File Format:

xlsx

Filename:

Lvov halloysite data.zip (600.2 KB)

Dataset Downloads:

3

Clay nanotube Pickering emulsions for spill oil bioremediation and catalytic formulations



Identification Information
Distribution Information
Metadata Maintenance Information

Metadata: 
  File identifier: 
      R5.x288.000-0001-metadata.xml
  Language: 
      eng; USA
  Character set: 
    Character set code: 
      utf8
  Hierarchy level: 
    Scope code: 
      dataset
  Metadata author: 
    Responsible party: 
      Individual name: 
          Yuri M. Lvov
      Organisation name: 
          Louisiana Tech University / Institute for Micromanufacturing
      Position name: 
          Professor
      Contact info: 
        Contact: 
          Phone: 
            Telephone: 
              Voice: 
                  3182575144
              Facsimile: 
          Address: 
            Address: 
              Delivery point: 
                  911 Hergot Ave
              City: 
                  Ruston
              Administrative area: 
                  Louisiana
              Postal code: 
                  71272
              Country: 
                  USA
              Electronic mail address: 
                  ylvov@latech.edu
      Role: 
        Role code: 
          pointOfContact
  Date stamp: 
      2021-05-04T20:04:56+00:00
  Metadata standard name: 
      ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
  Metadata standard version: 
      ISO 19115-2:2009(E)
  Dataset URI: 
      https://data.gulfresearchinitiative.org/metadata/R5.x288.000:0001
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Identification info: Data identification: Citation: Citation: Title: Clay nanotube Pickering emulsions for spill oil bioremediation and catalytic formulations Alternate title: Date: Date: Date: 2016-05-25 Date type: Date type code: publication Identifier: Identifier: Code: Anchor: xlink: https://dx.doi.org/10.7266/N73X8533 title: DOI doi:10.7266/N73X8533 Abstract: The data involves chiefly, the use of halloysite clay nanotubes (HNT) in forming Pickering emulsions with oil and water. The halloysites were functionalised using octadecyltrimethoxysilane (ODTMS) and hexadimethylsilane (HMDS) in order to hydrophobize the halloysite and form better Pickering emulsions. The bacterial affinity of halloysites in general and modified halloysite was tested using the bacterial strain, Alcanivorax borkumensis. The bacteria was obtained from ATCC and was used in several toxicity and emulsion experiments. The onus of the study was to study the affinity of the oil-degrading bacteria to HNTs and hydrophobized HNT and the resultant toxicity. Purpose: Developing better herding and dispersant systems for oil bioremediation using halloysite clay nanotubes Status: Progress code: completed Point of contact: Responsible party: Individual name: Yuri M. Lvov Organisation name: Louisiana Tech University / Institute for Micromanufacturing Position name: Professor Contact info: Contact: Phone: Telephone: Voice: 3182575144 Facsimile: Address: Address: Delivery point: 911 Hergot Ave City: Ruston Administrative area: Louisiana Postal code: 71272 Country: USA Electronic mail address: ylvov@latech.edu Role: Role code: principalInvestigator Descriptive keywords: Keywords: Keyword: halloysite Keyword: oil Keyword: bioremediation Keyword: dispersant Keyword: toxicity Type: Keyword type code: theme Descriptive keywords: Keywords: Keyword: inapplicable Type: Keyword type code: place Resource constraints: title: Cite As Constraints: Use limitation: Renata Munillina, Abhishek Panchal, Yuri Lvov, Rawil Fakhrullin. 2016. Clay nanotube Pickering emulsions for spill oil bioremediation and catalytic formulations. Distributed by: Gulf of Mexico Research Initiative Information and Data Cooperative (GRIIDC), Harte Research Institute, Texas A&M University–Corpus Christi. doi:10.7266/N73X8533 Resource constraints: title: CC0 License Legal constraints: Use constraints: Restriction code: licenceUnrestricted Other constraints: This information is released under the Creative Commons license - No Rights Reserved - CC0 1.0 Universal (https://creativecommons.org/publicdomain/zero/1.0/). The person who associated a work with this deed has dedicated the work to the public domain by waiving all of his or her rights to the work worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law. You can copy, modify, distribute and perform the work, even for commercial purposes, all without asking permission. Resource constraints: title: Liability and Warranty Legal constraints: Other constraints: All materials on this website are made available to GRIIDC and in turn to you "as-is." Content may only be submitted by an individual who represents and warrants that s/he has sufficient rights to be able to make the content available under a CC0 waiver. There is no warranty (expressed or implied) to these materials, their title, accuracy, non-infringement of third party rights, or fitness for any particular purpose, including the performance or results you may obtain from their use. Use these materials at your own risk. Under no circumstances shall GRIIDC be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use or the inability to use either this website or the materials available via this website. If you are dissatisfied with any website feature, content, or terms of use, your sole and exclusive remedy is to discontinue use. Aggregation Info: AggregateInformation: Aggregate Data Set Name: title: Related Publication Citation Citation: Title: Von Klitzing, R., Stehl, D., Pogrzeba, T., Schomäcker, R., Minullina, R., Panchal, A., … Lvov, Y. (2016). Halloysites Stabilized Emulsions for Hydroformylation of Long Chain Olefins. Advanced Materials Interfaces, 4(1), 1600435. doi:10.1002/admi.201600435 Date: inapplicable Aggregate Data Set Identifier: title: Related Publication DOI Identifier: Code: Anchor: xlink: https://dx.doi.org/10.1002/admi.201600435 title: DOI doi:10.1002/admi.201600435 Association Type: Association type code: crossReference Language: eng; USA Topic category: Topic category code: biota Topic category: Topic category code: environment Extent: Extent: Description: The work is related to developing an efficient oil-dispersant and bioremediation formulation with halloysite clay nanotubes which is designed to work in any place of oil spill. This dataset contains laboratory data, no field sampling involved. Supplemental Information: Data for figure 2A.xlsx: halloysite concentration (0.25wt.%, 0.5wt.%, or 1wt.%), diameter of Pickering emulsions (um), vortex time (1 min, 3 min). Data for figure 2B.xlsx: halloysite concentration (0.25wt.%, 0.5wt.%, or 1wt.%), diameter of Pickering emulsions (um), time-days after emulsification formation (1, 3, 7). Data for figure 4.xlsx: 1wt.% halloysite (short, medium, or long), diameter of Pickering emulsions (um), probability Data for figure 6.xlsx: solution (Emulsions with 14a halloysites functionalized with hexadimethylsilane (HMDS) and plain deionized water; Emulsions with 14a halloysites functionalized with hexadimethyldislazane (HMDS) and 0.2M NaCl solution; Emulsions with 14a halloysites functionalized with hexadimethyldislazane (HMDS) and 0.6M NaCl solution; Emulsions with pristine, non-functionalized 14a halloysites and plain deionized water; Emulsions with pristine, non-functionalized 14a halloysites and 0.2M NaCl solution; Emulsions with pristine, non-functionalized 14a halloysites and 0.6M NaCl solution; Emulsions with 14a halloysites functionalized with octadecyltrimethoxysilane (ODTMS) and plain deionized water; Emulsions with 14a halloysites functionalized with octadecyltrimethylsilane (ODTMS) and 0.2M NaCl solution; Emulsions with 14a halloysites functionalized with octadecyltrimethylsilane (ODTMS) and 0.6M NaCl solution), probability, diameter of Pickering emulsions(um). Data for figure 9.xlsx: Time (hours passed, t0 = start), halloysite concentration (0.5mg/mL, 1 mg/mL, 1.5 mg/mL, 2.5 mg/mL),optical density (absorbance) of bacterial suspensions. Definitions of codes used in data files: Code (concentration) [definition]: US (0.25%, 0.5%, 1%) [halloysites from batch # 1 acquired from Applied Minerals Inc, NY followed by percentages by weight]; 14a (0.25%, 0.5%, 1%) [halloysites from batch # 14a acquired from Applied Minerals Inc, NY followed by percentages by weight]; Short HNT [Short length halloysite clay nanotubes]; Medium HNT [Medium length halloysite clay nanotubes]; Long HNT [Long length halloysite clay nanotubes]; 14a-HMDS H2O [Emulsions with 14a halloysites functionalized with hexadimethyldislazane (HMDS) and plain deionized water]; 14a-HMDS (0.2M, 0.6M) [Emulsions with 14a halloysites functionalized with hexadimethyldislazane (HMDS) and 0.2M 0.6M NaCl solutions respectively]; 14a-ODTMS H2O [Emulsions with 14a halloysites functionalized with octadecyltrimethylsilane (ODTMS) and plain deionized water]; 14a-ODTMS (0.2M, 0.6M)[Emulsions with 14a halloysites functionalized with octadecyltrimethylsilane (ODTMS) and 0.2M 0.6M NaCl solutions respectively]; Pristine 14a H2O [Emulsions with pristine, non-functionalized 14a halloysites and plain deionized water); Pristine 14a (0.2M, 0.6M) (Emulsions with pristine, non-functionalized 14a halloysites and 0.2M 0.6M NaCl solutions respectively]; Bare H20, [Emulsions with pristine, non-functionalized 14a halloysites and plain deionized water]; Bare (0.2 M, 0.6 M) [Emulsions with pristine, non-functionalized 14a halloysites and 0.2M 0.6M NaCl solutions respectively]; control [Control sample with no halloysite];0,5 mg/ml [Sample with 0.5mg/mL halloysites]; 1 mg/ml [Sample with 1 mg/mL halloysites]; 1,5 mg/ml [Sample with 1.5mg/mL halloysites]; 2,5 mg/ml [Sample with 2.5mg/mL halloysites]|Data for figure 2A.xlsx: Halloysite was added to model Gulf oil in water (with a ratio of 1:3), measurements were collected the same day. Data for figure 2B.xlsx: Halloysite was added to model Gulf oil in water (with a ratio of 1:3). Data for figure 4.xlsx: Hydrophobized halloysite was added to pure water, measurements were collected after 1 week. Data for figure 6.xlsx: Halloysite was added to either pure water, 0.2 M NaCl or 0.6 M NaCl and measurements were collected after 1 week. Data for figure 9.xlsx: Halloysite was added to Alcanivorax borkumensis cells, measurements were made in real time.||||
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Distribution info: Distribution: Distributor: Distributor: Distributor contact: Responsible party: Organisation name: Gulf of Mexico Research Initiative Information and Data Cooperative (GRIIDC) Contact info: Contact: Phone: Telephone: Voice: 3618253604 Address: Address: Delivery point: 6300 Ocean Drive City: Corpus Christi Administrative area: TX Postal code: 78412 Country: USA Electronic mail address: griidc@gomri.org Online Resource: Online Resource: Linkage: URL: https://data.gulfresearchinitiative.org Role: Role code: distributor Distributor format: Format: Name: xlsx Version: inapplicable File decompression technique: zip Distributor transfer options: Digital transfer options: Transfer size: 0.6002 Online: Online Resource: Linkage: URL: https://data.gulfresearchinitiative.org/data/R5.x288.000:0001 Protocol: https Name: Data Landing Page Description: GRIIDC dataset landing page Function: Online function code: information
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Metadata maintenance: Maintenance information: Maintenance and update frequency: unknown Maintenance note: This ISO metadata record was automatically generated from information provided to GRIIDC for dataset: R5.x288.000:0001 on 2021-10-20T12:06:26-05:00
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